This report documents the results of a systematic study on the stress corrosion cracking scc susceptibility of austenitic stainless steel exposed to these species. Why chloride stress corrosion cracking only obeserved in. Quote stress corrosion cracking a closeup of the surface of a steel pipeline showing indications o. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. The strength and corrosion resistance of duplex stainless steel are achieved with a lower alloy content than equivalent austenitic grades. This type of steel also provides excellent resistance against stress corrosion cracking when brought in contact with 2040% boiling sulfuric acid. Aluminum alloys most often associated with stresscorrosion cracking in actual service are 2014, 2024, 2219, 7075, 7079, and 7178 alloys, and cast alloys of ternalloy 7, 40e, 195, and 220 compositions. Stress corrosion cracking of austenitic stainless steel under. Chloride induced stress corrosion cracking of stainless steel. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that. Stress corrosion cracking needs a sustained load and a. It is postulated that with sufficient ambient humidity, scc could initiate by deliquescence of species on the canister surface, particularly at locations such as welds.
Duplex steel have improved strength over austenitic stainless steels and also improved resistance to localized corrosion particularly pitting, crevice corrosion and stress corrosion cracking. Residual stress is produced by initial metal forming and welding operations although a good welding procedure will avoid this problem by properly annealing the heated area. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Also, this stainless steel exhibits excellent mechanical properties and the presence of niobium helps to. It appears that stress corrosion cracking in austenitic stainless steels in the presence of chlorides proceeds transgranularly and usually occurs at temperature above 70c 39, 40.
A complete guide to stainless steel metal casting resources. Prevention of external chloride stress corrosion cracking. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The general corrosion and stress corrosion behavior of fe27ni15cr5al2mo0. Type 304 is the most widely used alloy of all stainless steels. Applications of fracture mechanics in stress corrosion cracking and introduction to. From this point of view, super austenitic stainless steel is the best material choice in the most dangerous oil and gas environment with a large amount of hydrogen sulfide. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10. Inter granular corrosion can be detected by ultrasonic and eddy current methods.
Stress corrosion cracking scc of austenitic stainless and. Chloride induced stress corrosion cracking of stainless. This alloy exhibits superior resistance to stresscorrosion cracking in boiling 2040% sulfuric acid. Effect of halogens and inhibitors on the external stress. Ferritic stainless steel is known for its greater ductility, formability, and resistance to stress corrosion cracking, and these alloys are normally part of the 400 series.
When austenitic stainless steel is heated such as welding or slowly cooled in this temperature range for a long time, intergranular corrosion sensitivity is generated. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. The most common environment that causes pitting, crevice corrosion and stress corrosion cracking in stainless steel is in water, especially in.
Stress corrosion cracking of austenitic stainless steel weldments. Prevention of external chloride stress corrosion cracking of. This diagram figure 1 is analogous to a similar diagram for caustic. Pdf exploring factors controlling precorrosion fatigue. Stresscorrosion cracking of insulating jackets often results from airborne salts in coastal regions. Mili24244 is a us dept of defense specification for insulation that is going to be used on the stainless steel pipe and equipment associated with nuclear propulsion.
Austenitic stainless steels chloride induced stress. Chloride stress corrosion cracking in austenitic stainless steel. Stress corrosion cracking international institute of. For example, the cracking morphology of austenitic stainless steel in 50% naoh solution has nothing to do with heat treatment, but is transgranular cracking.
Stress corrosion cracking the international institute of. Austenitic steel is sensitive to this type of corrosion above 60c in the presence of dissolved oxygen. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Because stress intensity is a critical factor, scc cracks often initiate at. Stress corrosion cracking scc occurs when simultaneous action of a sustained tensile stress and a corrosive environment act to propagate sharp cracks through an aluminum part with a susceptible microstructure. Cracking of stainless steel nozzle sleeve metallurgical. Corrosion assisted fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel summary. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
Stress corrosion cracking of aisi 304 and aisi 316 austenitic. The corrosion and stress corrosion cracking behavior of a. Oct 08, 20 thermowells can breathe in atmospheric moisture. This is a chromiumnickel stainless that also contains alloying additions such as aluminum, copper or titanium. Use of aluminum foil for prevention of stress corrosion. Austenitic steels are nonmagnetic stainless steels that contain high levels of chromium and nickel and low levels of carbon. Oct 29, 2017 this type of steel also provides excellent resistance against stress corrosion cracking when brought in contact with 2040% boiling sulfuric acid.
Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Metallurgical influences on stress corrosion cracking. Also, this stainless steel exhibits excellent mechanical properties and the presence of niobium helps to minimize carbide precipitation during welding. Chloride stress corrosion cracking in austenitic stainless.
The following excerpt from wikipedia article will clarify it further. The effect of cold work on stress corrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Stress corrosion cracking scc of austenitic stainless steel weld metal. All thermal spraying processes rely on the same principle of heating a feedstock, accelerating it to a high velocity, and. Duplexes have higher yield strength and greater stress corrosion cracking resistance to chloride than austenitic stainless steels. A cracked nozzle sleeve stub from a chemical processing vessel of the proprietary vaporizer system was analyzed to determine the cause of cracking. Stress corrosion cracking of an austenitic stainless steel. Things to consider when choosing a stainless steel grade.
Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation. The use of austenitic stainless steel should be kept to a minimum. The dozens of alloy variants make welding stainless steel more complicated than welding traditional carbon steel. Sensitization and testing for intergranular corrosion.
Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Oct 29, 2017 austenitic steel is a type of stainless steel that contains austenite. Temperature is a significant environmental factor affecting cracking. However, the presence of dissolved oxygen in geothermal fluids would cause stress corrosion of austenitic stainless steel. Duplex stainless steels are regularly used to produce parts for chlorideexposed applications in the desalination and petrochemical industry. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Stainless steel the four types of steel metal supermarkets. A phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stress corrosion cracking scc.
Duplex stainless steels have high resistance to localized corrosion particularly pitting, crevice corrosion, and stress corrosion cracking. The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. Stress corrosion cracking scc susceptibility of austenitic en1. Tensile stresses, both residual and applied, are usually present in cold equipment. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Transgranular stress corrosion cracking an overview.
Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Alloy 20 carpenter 20 is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless. Stress corrosion cracking of insulating jackets often results from airborne salts in coastal regions. Properties of super austenitic stainless steel metal. How to avoid caustic cracking of carbon steel and low. Stress corrosion cracking of austenitic stainless steels in. This type is the most popular and favorable metal for industrial purposes. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Jan 03, 2019 they are defined by the presence of alloying elements molybdenum, aluminum, andor titanium in addition to the chromium and nickel found in austenitic grades.
The aluminum will also corrode where its exposed surface contacts the brass plate because brass is more cathodic. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Austenitic steel is a type of stainless steel that contains austenite. This paper discusses various cases of scc and stress induced cracking sic that normally occur with austenitic stainless steel in fertilizer plants and describes three case studies. All thermal spraying processes rely on the same principle of heating a feedstock, accelerating it to a high velocity, and then allowing the particles to strike the substrate. Even here, stress corrosion cracking sccmay occur due to contamination, either of the product in the pipe or vessel or externally from sea water, particularly where the liquid is able to concentrate in crevices. Practical immunity to chloride stress corrosion cracking. The next most popular class is known as ferritic stainless steel, and these alloys have molybdenum, aluminum, andor titanium added in addition to chromium and nickel. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. It contains a high percentage of nickel and chromium, enhancing its ability to be formed and welded easily into any shape along with providing great strength and resistance to corrosion. Specimens with surface residual compressive stress, ubend specimens, and notched compressive specimens of modified wol type were used.
It also cathodically protects stainless steel in the event of flooding of the lagging system, thereby preventing initiation of pitting and stress corrosion cracking. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that are dominated by either stress, scc, or. Materials corrosion under insulation cui thermal spray. The combination of alloying elements gives the stainless steel greater ductility and resistance to stress corrosion cracking. Stress corrosion cracking of austenitic stainless steel in. Caustic stress corrosion cracking inspectioneering. Chlorides will not cause scc unless an aqueous phase is present. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e.
Stress corrosion cracking of aisi 304 and aisi 316. Stress corrosion cracking scc of duplex stainless steel. When the use of such a material cannot be avoided, and where there is danger of transgranular stress corrosion cracking, the use of higher alloy materials such as stabilized incoloys or ferritic stainless steel such as type 444 18 cr2 mo. Its corrosion products are loose, porous, nonlayered magnetic oxides, and. The austenitic stainless steel series 300 is more susceptible in an environment containing chlorides. Known for their formability and resistance to corrosion, austenitic steels are the most widely used grade of stainless steel. Laboratory data are presented that confirm the galvanic protection afforded by the foil, and the efficiency of the foil in. They are defined by the presence of alloying elements molybdenum, aluminum, andor titanium in addition to the chromium and nickel found in austenitic grades. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. They are characterized by high chromium and lower nickel contents than austenitic stainless steels. Intergranular corrosion stainless steel tubing manufacturer. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Overview the fe21cr24ni6mo uns n08367 alloy was designed to be a seawater resistant alloy and has been successfully used in a multitude of marine and offshore applications including process piping systems, heat exchanger equipment. Stress corrosion cracking of austenitic stainless steel. In this paper, experimental results on stress corrosion cracking in austenitic stainless steels are described. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Stress corrosion cracking an overview sciencedirect topics. On the stress corrosion cracking mechanisms of austenitic. Known for its corrosion resistance and wide range of uses in food handling, cutlery, and many other applications, stainless steel is one of the most popular metals in use today. Austenitic stainless steels are therefore not generally used where halides are present. The aluminum plate will corrode more heavily due to it being more anodic to stainless steel than brass is. To characterize the corrosion type as well the extent of corrosion, the corrosion behavior of 316l austenitic stainless steel at different hf concentrations are investigated. Stabilized to prevent intergranular corrosion as welded. Stress corrosion cracking scc is a common issue with many specialty alloys.
Corrosion of austenitic stainless steels 1st edition. Its popularity also derives from many other advantages, including a high strengthtoweight ratio, excellent formability, and low maintenance requirements. Stress corrosion cracking scc of austenitic stainless steel in boiling 42% mgcl 2 solution under compressive stress was investigated. The effect of cold work on the stresscorrosion cracking.
Stress crack corrosion is not only limited to austenitic stainless steel. Ferritic stainless steel has reduced corrosion resistance compared to austenitic grades, but fares better than martensitic stainless steel. Solutions containing less than 1 ppm are normally considered safe. Crack growth data in sodium chloride solution for aisi 304 steel obtained for different metallurgical conditions, acoustic emission data recorded during crack growth and fractographic observations have been discussed with a view to identifying the operating mechanism. Sulfide stress cracking experimental investigations and observations in the field have shown that even highstrength steels are susceptible to cracking when simultaneously stressed and exposed to aqueous solutions of h 2 s. Standard recommended practice austenitic stainless steels. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Stainless steel is obviously best known for its corrosion resistance, but there is a lot more to the metal than just a single attribute. The probability of failure and the speed of crack propagation are governed by the temperature of the stainless steel and the chloride concentration at the metal surface. Control methods for the stainless steel corrosion generally have considered two factors.